1-[(Z)-1-Bromo-2-(butyldichloro-lambda(4)tellanyl)ethenyl]cyclohex-1-ene

1-[(Z)-1-Bromo-2-(butyldichloro-lambda(4)tellanyl)ethenyl]cyclohex-1-ene

Author Zukerman-Schpector, Julio Google Scholar
Caracelli, Ignez Google Scholar
Guadagnin, Rafael Carlos Autor UNIFESP Google Scholar
Stefani, Helio A. Google Scholar
Tiekink, Edward R. T. Google Scholar
Institution Universidade Federal de São Carlos (UFSCar)
Universidade Federal de São Paulo (UNIFESP)
Universidade de São Paulo (USP)
Univ Malaya
Abstract The Te-IV atom in the title compound, [Te(C4H9)(C8H10Br)Cl-2] or C12H19BrCl2Te, is in a distorted psi-trigonal-bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48 (4)degrees]. Close intramolecular [Te center dot center dot center dot Br = 3.3444 (18) angstrom] and intermolecular [Te center dot center dot center dot Cl = 3.675 (3) angstrom] interactions are observed. the latter lead to centrosymmetric dimers which assemble into layers in the bc plane. the primary connections between layers are of the type C-H center dot center dot center dot Cl.
Language English
Sponsor Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
Grant number FAPESP: 07/59404-2
CNPq: 306532/2009-3
CNPq: 308116/2010-0
CAPES: 808/2009
Date 2011-07-01
Published in Acta Crystallographica Section E-structure Reports Online. Hoboken: Wiley-Blackwell, v. 67, p. O1751-U1249, 2011.
ISSN 1600-5368 (Sherpa/Romeo, impact factor)
Publisher Wiley-Blackwell
Extent O1751-U1249
Origin http://dx.doi.org/10.1107/S1600536811023142
Access rights Open access Open Access
Type Article
Web of Science ID WOS:000294663200108
URI http://repositorio.unifesp.br/handle/11600/33824

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